Explosive Limits of Common Combustible Gases and Vapors


The range of concentrations of combustible gases and vapours, defined by lower and upper explosive limits expressed as a percentage of the total volume, are those capable of being detonated or ignited by an energy source. The following table gives upper and lower limits of the more common gases determined at atmospheric pressure and where possible room temperature. (The upper limit some vapours were determined at higher temperature because of their low vapour pressures).

The sources of reference are: BS5345 Part 1: 1976 Table 5 ‘Combustion Flame and Explosion of Gases” B. Lewis and CL Von FIbe, Academic Press (1951) 


Name

Formula

Explosive Limits % LEL

Explosive Limits v/v UEL

Acetaldehyde

CH3CHO

4.0

57.0

Acetic Acid

CH3COOH

5.4

*

Acetone

CH3COCH3

2.15

12.8

Acetylene

CH = CH

1.5

80.0

Ammonia

NH3

15.0

27.0

Benzene

C6H6

1.2

7.1

Butane

C4H10

1.5

8.4

Butanol

C4H9OH

1.7

11.25

Carbon Monoxide

CO

12.5

74.2

Dichloroethane

CH2ClCH2Cl

5.6

15.9

Ethane

C2H6

3.0

12.5

Ethanol

C2H5OH

3.3

18.95

Ethene

CH2 =CH2

2.7

28.6

Heptane

C7H16

1.1

6.7

Hexane

C6H14

1.2

7.4

Hydrogen

H2 4.0

4.0

74.2

Hydrogen Sulphide

H2S

4.3

45.5

Methane

CH4

5.0

15.0

Methanol

CH3OH

6.7

36.5

Pentane

C5H12

1.4

7.8

Propane

C3 H 8

2.0

9.35

Propanol

C3H 70H

2.15

13.5

Propylene

CH3CH = CH2

2.0

11.1

Toluene

C6H5CH3

1.2

6.75