The range of concentrations of combustible gases and vapours, defined by
lower and upper explosive limits expressed as a percentage of the total volume,
are those capable of being detonated or ignited by an energy source. The following
table gives upper and lower limits of the more common gases determined at atmospheric
pressure and where possible room temperature. (The upper limit some vapours were
determined at higher temperature because of their low vapour pressures).
The sources of reference are: BS5345 Part 1: 1976 Table 5 ‘Combustion Flame and Explosion of Gases” B. Lewis and CL Von FIbe, Academic Press (1951)
Name |
Formula |
Explosive Limits % LEL |
Explosive Limits v/v UEL |
Acetaldehyde |
CH3CHO |
4.0 |
57.0 |
Acetic Acid |
CH3COOH |
5.4 |
* |
Acetone |
CH3COCH3 |
2.15 |
12.8 |
Acetylene |
CH = CH |
1.5 |
80.0 |
Ammonia |
NH3 |
15.0 |
27.0 |
Benzene |
C6H6 |
1.2 |
7.1 |
Butane |
C4H10 |
1.5 |
8.4 |
Butanol |
C4H9OH |
1.7 |
11.25 |
Carbon Monoxide |
CO |
12.5 |
74.2 |
Dichloroethane |
CH2ClCH2Cl |
5.6 |
15.9 |
Ethane |
C2H6 |
3.0 |
12.5 |
Ethanol |
C2H5OH |
3.3 |
18.95 |
Ethene |
CH2 =CH2 |
2.7 |
28.6 |
Heptane |
C7H16 |
1.1 |
6.7 |
Hexane |
C6H14 |
1.2 |
7.4 |
Hydrogen |
H2 4.0 |
4.0 |
74.2 |
Hydrogen Sulphide |
H2S |
4.3 |
45.5 |
Methane |
CH4 |
5.0 |
15.0 |
Methanol |
CH3OH |
6.7 |
36.5 |
Pentane |
C5H12 |
1.4 |
7.8 |
Propane |
C3 H 8 |
2.0 |
9.35 |
Propanol |
C3H 70H |
2.15 |
13.5 |
Propylene |
CH3CH = CH2 |
2.0 |
11.1 |
Toluene |
C6H5CH3 |
1.2 |
6.75 |